Search Results - "ASOKAN, C. V."
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Synthesis of Multi(metallo)porphyrin Dendrimers through Nucleophilic Aromatic Substitution on meso-Pyrimidinyl Substituted Porphyrins
Published in Journal of organic chemistry (14-04-2006)“…A convergent synthetic strategy toward novel all-porphyrin dendrimers, which can be regarded as synthetic model systems of the natural photosynthetic…”
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Synthesis of 2,3,5-trisubstituted furans from α-formylaroylketene dithioacetals
Published in Tetrahedron letters (06-04-2011)“…A new strategy for the synthesis of 2,3,5-trisbustituted furans from α-formylketene dithioacetals is described. The protocol involves a facile conversion of…”
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Synthesis of pyrimidine-5-carbaldehydes from α-formylaroylketene dithioacetals
Published in Tetrahedron (13-08-2007)“…A facile one pot synthetic path for the preparation of pyrimidine-5-carbaldehydes from α-formylaroylketene dithioacetals is described. Amidines were allowed to…”
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2-[2-(4-Methyl-benzo-yl)-3,3-bis-(methyl-sulfan-yl)prop-2-enyl-idene]malononitrile
Published in Acta crystallographica. Section E, Structure reports online (15-02-2008)“…The title compound, C(16)H(14)N(2)OS(2), is an example of a push-pull butadiene in which the electron-releasing and electron-withdrawing attachments on either…”
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5
Synthesis and Functionalization of Double Picket Fence Porphyrins Starting from 4,6-Disubstituted Pyrimidine-5-carbaldehydes
Published in Journal of organic chemistry (08-09-2000)Get full text
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Ultrasonic investigation of molecular interaction in binary mixtures of nitriles with methanol/toluene
Published in The Journal of chemical thermodynamics (01-01-2000)“…Ultrasonic velocity, density, and viscosity have been measured in the binary mixtures of nitriles with (CH3OH / C6H5CH3) at different temperatures. Excess…”
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An efficient synthesis of highly substituted pyrroles from β-oxodithiocarboxylates
Published in Tetrahedron (20-02-2006)“…α-Oxoketene- N, S-acetals, prepared by the reaction of alkyl glycinate hydrochlorides with β-oxodithiocarboxylates followed by alkylation, underwent…”
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Cyclization of functionalized ketene- N, S-acetals to substituted pyrroles: applications in the synthesis of marine pyrrole alkaloids
Published in Tetrahedron letters (17-01-2005)“…[Display omitted] α-Oxoketene- N, S-acetals, prepared by the reaction of alkyl glycinates with β-oxodithiocarboxylates followed by alkylation, underwent…”
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Vilsmeier–Haack reactions of α-hydroxyketenedithioacetals: a facile synthesis of substituted pyridines
Published in Tetrahedron letters (18-03-2002)“…The reaction of α-hydroxyketenedithioacetals, generated by the 1,2-addition of methyl Grignard reagent to α-oxoketenedithioacetals, with the Vilsmeier reagent…”
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Vilsmeier–Haack reactions of carbonyl compounds: synthesis of substituted pyrones and pyridines
Published in Tetrahedron (31-05-2004)“…Vilsmeier–Haack reaction of substituted phenylacetones leads to the formation of conjugated iminium salts which on aqueous basic work up afford…”
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11
Sterically encumbered triarylcorroles from aryldipyrromethanes and aromatic aldehydes
Published in Tetrahedron letters (02-07-2001)“…A two-step synthesis of corroles from dipyrromethanes and aromatic aldehydes has been achieved. Acid-catalyzed [2+2] condensation of…”
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12
Synthesis of Multi(metallo)porphyrin Dendrimers through Nucleophilic Aromatic Substitution on m eso-Pyrimidinyl Substituted Porphyrins
Published in Journal of organic chemistry (14-04-2006)“…A convergent synthetic strategy toward novel all-porphyrin dendrimers, which can be regarded as synthetic model systems of the natural photosynthetic…”
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13
Novel phototransformations of bridgehead-dimethyl-substituted dibenzobarrelene. Structure of the photoproducts
Published in Journal of organic chemistry (01-09-1991)Get full text
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14
Bromine Complexes of Polyvinylpyrrolidone Supports: A Mild Reagent for the Transformation of α-Oxoketene Dithioacetals to β-Oxothiolesters
Published in Synthetic communications (01-08-2005)“…When α-oxoketene dithioacetals 1a-n were treated with the bromine complex of a copolymer of 1-vinyl-2-pyrrolidone and 4-vinylpyridine, the corresponding…”
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15
A FACILE SYNTHESIS OF β-OXOTHIOLCARBOXYLATES FROM α-OXOKETENEDITHIOACETALS
Published in Synthetic communications (01-01-2001)“…α-Oxoketenedithioacetals and alkenoyl ketenedithioacetals underwent facile, boron trifluoride etherate assisted partial hydrolysis in dioxane to afford…”
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Sulfhydrolysis of Acyl Ketene Dithioacetals: A Convenient Synthesis of β-Oxodithioesters
Published in Synthetic communications (01-03-1999)“…β-Oxodithioesters are obtained in good yields from acyl ketenedithioacetals on treatment with hydrogen sulphide in the presence of boron trifluoride eiherate…”
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A facile method for the synthesis of substituted 2-ylidene-1,3-oxathioles from acetophenones
Published in Tetrahedron letters (19-11-2007)“…Compounds incorporating 1,3-oxathiole moieties in their frameworks are biologically active. Active methylene ketones can be easily converted to the…”
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18
Reactions of 1-aryl-2-propanones with chloromethyleneiminium salt
Published in Tetrahedron letters (01-12-1997)“…A synthesis of 3-formyl-4-pyrones by Vilsmeier-Haack reaction of substituted benzyl methyl ketones has been reported. The reaction of benzyl ethyl ketone with…”
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Microwave assisted one-pot synthesis of pyrrolo[2,1-b]thiazol-6-ones from α-aroyl ketene-N,S-acetals
Published in Journal of heterocyclic chemistry (01-03-2010)“…α‐Aroyl ketene‐N,S‐acetals 3 prepared by the reaction of β‐oxothioamides 1 with phenacyl bromides 2, underwent sequential cyclizations under microwave…”
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Phototransformations of Bridgehead-Disubstituted Dibenzobarrelenes. Interesting Rearrangements of Dibenzosemibullvalene Intermediates Derived from 9-(Hydroxyalkyl)-10-methoxy-Substituted Dibenzobarrelenes1
Published in Journal of organic chemistry (09-08-1996)“…The photochemistry of 11,12-dibenzoyl-9,10-dihydro-9-(hydroxymethyl)-10-methoxy-9,10-ethenoanthracene (7a) and…”
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