Search Results - "ASAO, Naoki"
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Nanocatalysts Fabricated by a Dealloying Method
Published in Chemical record (01-10-2015)“…Two types of nanomaterials with different morphologies are described in this article: nanoporous metals and titanate nanowires. Both materials are fabricated…”
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Atomic origins of the high catalytic activity of nanoporous gold
Published in Nature materials (01-09-2012)“…Distinct from inert bulk gold, nanoparticulate gold has been found to possess remarkable catalytic activity towards oxidation reactions. The catalytic…”
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Pd-Catalyzed Synthesis of 9,9′-Bifluorenylidene Derivatives via Dual C–H Activation of Bis-biaryl Alkynes
Published in Journal of the American Chemical Society (09-07-2014)“…We report a novel Pd-catalyzed alkyne-directed dual C–H activation of bis-biaryl alkynes, which produced important and useful products, 9,9′-bifluorenylidene…”
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Pd-Catalyzed Cascade Crossover Annulation of o‑Alkynylarylhalides and Diarylacetylenes Leading to Dibenzo[a,e]pentalenes
Published in Journal of the American Chemical Society (17-07-2013)“…A novel and selective Pd-catalyzed cascade crossover-annulation of o-alkynylarylhalides and diarylacetylenes for the synthesis of dibenzo[a,e]pentalenes has…”
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Lewis Acid-Catalyzed [4 + 2] Benzannulation between Enynal Units and Enols or Enol Ethers: Novel Synthetic Tools for Polysubstituted Aromatic Compounds Including Indole and Benzofuran Derivatives
Published in Journal of organic chemistry (07-07-2006)“…The reaction of enynals 1, including o-(alkynyl)benzaldehydes, and carbonyl compounds 2, such as aldehydes and ketones, in the presence of a catalytic amount…”
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Remarkable Catalytic Property of Nanoporous Gold on Activation of Diborons for Direct Diboration of Alkynes
Published in Organic letters (15-11-2013)“…A novel catalytic property of nanoporous gold for activation of bis(pinacolato)diboron has been reported that allows the direct diboration of alkynes to…”
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Bottom-Up Graphene-Nanoribbon Fabrication Reveals Chiral Edges and Enantioselectivity
Published in ACS nano (23-09-2014)“…We produce precise chiral-edge graphene nanoribbons on Cu{111} using self-assembly and surface-directed chemical reactions. We show that, using specific…”
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AuCl-Catalyzed [4+2] Benzannulation between o-Alkynyl(oxo)benzene and Benzyne
Published in Organic letters (09-11-2006)“…The AuCl-catalyzed benzannulation of o-alkynyl(oxo)benzenes with benzenediazonium 2-carboxylate proceeds under mild conditions and a variety of anthracene…”
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Nanoporous Gold Catalyst for Highly Selective Semihydrogenation of Alkynes: Remarkable Effect of Amine Additives
Published in Journal of the American Chemical Society (24-10-2012)“…We report for the first time the highly selective semihydrogenation of alkynes using the unsupported nanoporous gold (AuNPore) as a catalyst and organosilanes…”
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Self-Assembly Strategy for Fabricating Connected Graphene Nanoribbons
Published in ACS nano (22-12-2015)“…We use self-assembly to fabricate and to connect precise graphene nanoribbons end to end. Combining scanning tunneling microscopy, Raman spectroscopy, and…”
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AuBr3- and Cu(OTf)2-Catalyzed Intramolecular [4 + 2] Cycloaddition of Tethered Alkynyl and Alkenyl Enynones and Enynals: A New Synthetic Method for Functionalized Polycyclic Hydrocarbons
Published in Journal of organic chemistry (29-04-2005)“…Treatment of tethered alkynyl enynones 8, in which a carbon chain is attached to the carbonyl group, with a catalytic amount of AuBr3 in (ClCH2)2 gave the…”
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12
2-Positional pyrene end-capped oligothiophenes for high performance organic field effect transistors
Published in Chemical communications (Cambridge, England) (01-01-2016)“…Three new 2-positional pyrene end-capped oligothiophene co-oligomers, BPynT (n = 1, 2, 3), have been synthesized for application in organic field effect…”
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Cu-Catalyzed C–H Amination of Hydrofullerenes Leading to 1,4‑Difunctionalized Fullerenes
Published in Organic letters (17-01-2014)“…A novel and highly efficient Cu-catalyzed C–H amination of the monofunctionalized hydrofullerenes for the synthesis of 1,4-difunctional fullerenes has been…”
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Nanorheological Mapping of Rubbers by Atomic Force Microscopy
Published in Macromolecules (12-03-2013)“…A novel atomic force microscopy (AFM) method is used for nanometer-scale mapping of the frequency dependence of the storage modulus, loss modulus, and loss…”
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Unsupported Nanoporous Gold Catalyst for Highly Selective Hydrogenation of Quinolines
Published in Organic letters (05-04-2013)“…For the first time, the highly efficient and regioselective hydrogenation of quinoline derivatives to 1,2,3,4-tetrahydroquinolines using unsupported nanoporous…”
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Composition-Dependent Morphology of Bi- and Trimetallic Phosphides: Construction of Amorphous Pd–Cu–Ni–P Nanoparticles as a Selective and Versatile Catalyst
Published in ACS applied materials & interfaces (11-10-2017)“…Amorphous materials have been widely researched in heterogeneous catalysis and for next-generation batteries. However, the well-defined production of…”
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Hierarchical nanoporosity enhanced reversible capacity of bicontinuous nanoporous metal based Li-O2 battery
Published in Scientific reports (19-09-2016)“…High-energy-density rechargeable Li-O 2 batteries are one of few candidates that can meet the demands of electric drive vehicles and other high-energy…”
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Selective Aerobic Oxidation of Methanol in the Coexistence of Amines by Nanoporous Gold Catalysts: Highly Efficient Synthesis of Formamides
Published in Chemistry : a European journal (02-09-2013)“…Holey gold: Highly selective aerobic oxidation of methanol over alkylamines was achieved with a reusable nanoporous gold (AuNPore) catalyst that was fabricated…”
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Nanostructured Zr-Pd Metallic Glass Thin Film for Biochemical Applications
Published in Scientific reports (15-01-2015)“…Zr-Pd metallic glassy thin films with a hierarchical nano-scale structure, produced by magnetron sputtering of the Zr and Pd powder mixture, demonstrate a…”
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Induction of enantio-selective apoptosis in human leukemia HL-60 cells by (S)-erypoegin K, an isoflavone isolated from Erythrina poeppigiana
Published in Bioorganic & medicinal chemistry (01-06-2020)“…[Display omitted] •Isoflavone, (RS)-erypoegin K, was semi-synthesized as a racemic mixture.•(S)- and (R)-optical isomers were separated by chiral column…”
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