Search Results - "ANDERSON, Harry"
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Template-Directed Synthesis of Molecular Nanorings and Cages
Published in Accounts of chemical research (18-09-2018)“…Conspectus This Account is about templates as construction tools: molecules for making molecules. A template organizes the reactants and provides information…”
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An sp-hybridized molecular carbon allotrope, cyclo[18]carbon
Published in Science (American Association for the Advancement of Science) (20-09-2019)“…Carbon allotropes built from rings of two-coordinate atoms, known as cyclo[ ]carbons, have fascinated chemists for many years, but until now they could not be…”
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3
What is Cooperativity
Published in Angewandte Chemie (International ed.) (28-09-2009)“…The lamprey holds the clue to the link between supramolecular self‐assembly and allosteric ligand binding. Chelate cooperativity in self‐assembled structures…”
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4
Two-Photon Absorption and the Design of Two-Photon Dyes
Published in Angewandte Chemie (International ed.) (20-04-2009)“…Two photons are better than one: This principle applies to a wide range of applications, ranging from engineering to physiology. Recent advances in our…”
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5
Insulated Molecular Wires
Published in Angewandte Chemie International Edition (01-01-2007)“…An astonishing assortment of structures have been described as “insulated molecular wires” (IMWs), thus illustrating the diversity of approaches to…”
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6
Polymorphism and flexibility of six-porphyrin nanorings in the solid state
Published in Chemical science (Cambridge) (18-09-2024)“…Butadiyne-linked porphyrin nanorings are fascinating nanometer-sized platforms for exploring electronic delocalization and aromaticity, and they mimic…”
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7
From Macrocycles to Quantum Rings: Does Aromaticity Have a Size Limit?
Published in Accounts of chemical research (17-08-2021)“…Conspectus The ring currents of aromatic and antiaromatic molecules are remarkable emergent phenomena. A ring current is a quantum-mechanical feature of the…”
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8
Aromatic and antiaromatic ring currents in a molecular nanoring
Published in Nature (London) (12-01-2017)“…By investigating ring currents, a six-porphyrin nanoring molecule is shown to be antiaromatic in its 4+ oxidation state and aromatic in its 6+ oxidation state…”
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Experimental and Theoretical Evidence for Aromatic Stabilization Energy in Large Macrocycles
Published in Journal of the American Chemical Society (10-02-2021)“…Enhanced thermodynamic stability is a fundamental characteristic of aromatic molecules, yet most previous studies of aromatic stabilization energy (ASE) have…”
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Synthesis of Cyclo[18]carbon via Debromination of C18Br6
Published in Journal of the American Chemical Society (29-07-2020)“…Cyclo[18]carbon (C18, a molecular carbon allotrope) can be synthesized by dehalogenation of a bromocyclocarbon precursor, C18Br6, in 64% yield, by atomic…”
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11
Polyyne formation via skeletal rearrangement induced by atomic manipulation
Published in Nature chemistry (01-08-2018)“…Rearrangements that change the connectivity of a carbon skeleton are often useful in synthesis, but it can be difficult to follow their mechanisms. Scanning…”
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Synthesis and Properties of Porphyrin Nanotubes
Published in Helvetica chimica acta (01-01-2019)“…Discrete π‐conjugated zinc porphyrin nanotubes are investigated as molecular analogues of carbon nanotubes. These porphyrin nanotubes have a diameter of 2.4 nm…”
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13
A Short History of Cyclocarbons
Published in Bulletin of the Chemical Society of Japan (2021)“…The cyclocarbons constitute a family of molecular carbon allotropes consisting of rings of two-coordinate atoms. Their high reactivities make them difficult to…”
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Outcomes of Patients With Coronavirus Disease 2019 Receiving Organ Support Therapies: The International Viral Infection and Respiratory Illness Universal Study Registry
Published in Critical care medicine (01-03-2021)“…To describe the outcomes of hospitalized patients in a multicenter, international coronavirus disease 2019 registry. Cross-sectional observational study…”
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15
Molecular Quantum Rings Formed from a π -Conjugated Macrocycle
Published in Physical review letters (13-11-2020)“…The electronic structure of a molecular quantum ring (stacks of 40-unit cyclic porphyrin polymers) is characterized via scanning tunneling microscopy and…”
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16
Anthracene‐Porphyrin Nanoribbons
Published in Angewandte Chemie International Edition (01-08-2023)“…π‐Conjugated nanoribbons attract interest because of their unusual electronic structures and charge‐transport behavior. Here, we report the synthesis of a…”
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How do donor and acceptor substituents change the photophysical and photochemical behavior of dithienylethenes? The search for a water-soluble visible-light photoswitch
Published in Chemical science (Cambridge) (30-08-2023)“…Dithienylethenes are a type of diarylethene and they constitute one of the most widely studied classes of photoswitch, yet there have been no systematic…”
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NMDA spikes enhance action potential generation during sensory input
Published in Nature neuroscience (01-03-2014)“…In vitro evidence suggests that the tuft dendrites of pyramidal neurons can evoke local NMDA spikes. The authors find that these local NMDA spikes occur…”
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Polyyne Rotaxanes: Stabilization by Encapsulation
Published in Journal of the American Chemical Society (03-02-2016)“…Active metal template Glaser coupling has been used to synthesize a series of rotaxanes consisting of a polyyne, with up to 24 contiguous sp-hybridized carbon…”
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Bimolecular Sandwich Aggregates of Porphyrin Nanorings
Published in Journal of the American Chemical Society (11-09-2024)“…Extended π-systems often form supramolecular aggregates, drastically changing their optical and electronic properties. However, aggregation processes can be…”
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