Search Results - "Álvarez, Lucı́a"
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Nitric Oxide Is Reduced to HNO by Proton-Coupled Nucleophilic Attack by Ascorbate, Tyrosine, and Other Alcohols. A New Route to HNO in Biological Media?
Published in Journal of the American Chemical Society (15-04-2015)“…The role of NO in biology is well established. However, an increasing body of evidence suggests that azanone (HNO), could also be involved in biological…”
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The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes
Published in Coordination chemistry reviews (15-09-2015)“…•The synthesis, reactivity and catalytic activity of transition-metal derivatives of heavier tetrylene amidinates (amidinato-HT–TM complexes) are…”
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Biomass devolatilization at high temperature under N2 and CO2: Char morphology and reactivity
Published in Energy (Oxford) (01-11-2015)“…Oxy-fuel combustion is usually performed in pf reactors under an enriched O2 atmosphere of CO2 to obtain a high CO2 content in the flue gases. The effect of…”
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Structural basis for RAD18 regulation by MAGEA4 and its implications for RING ubiquitin ligase binding by MAGE family proteins
Published in The EMBO journal (02-04-2024)“…MAGEA4 is a cancer-testis antigen primarily expressed in the testes but aberrantly overexpressed in several cancers. MAGEA4 interacts with the RING ubiquitin…”
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Chemical Biology of Hydropersulfides and Related Species: Possible Roles in Cellular Protection and Redox Signaling
Published in Antioxidants & redox signaling (01-10-2017)“…For >20 years, physiological signaling associated with the endogenous generation of hydrogen sulfide (H S) has been of significant interest. Despite its…”
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Microchromosomes are building blocks of bird, reptile, and mammal chromosomes
Published in Proceedings of the National Academy of Sciences - PNAS (09-11-2021)“…Microchromosomes, once considered unimportant shreds of the chicken genome, are gene-rich elements with a high GC content and few transposable elements. Their…”
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Isocyanide Cu(I) complexes with unexpected μ2‐bridging pseudohalides: Synthesis, characterization and catalytic activity towards CuAAC
Published in Applied organometallic chemistry (01-08-2023)“…Three neutral Cu(I) complexes bearing 2,6‐dimethylphenyl isocyanide (CNXyl) and different triatomic pseudohalogens (SCN−, OCN− and N3−) as ligands were…”
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From a Diphosphanegermylene to Nickel, Palladium, and Platinum Complexes Containing Germyl PGeP Pincer Ligands
Published in Chemistry : a European journal (26-10-2017)“…The PGeP pincer‐type germylene Ge(NCH2PtBu2)C6H4 (1) has been used to prepare a family of group 10 metal complexes, namely,…”
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Assembly and comparative genome analysis of a Patagonian Aureobasidium pullulans isolate reveals unexpected intraspecific variation
Published in Yeast (Chichester, England) (01-05-2023)“…Aureobasidium pullulans is a yeast‐like fungus with remarkable phenotypic plasticity widely studied for its importance for the pharmaceutical and food…”
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Genetics and Epigenetics of Spontaneous Intracerebral Hemorrhage
Published in International journal of molecular sciences (09-06-2022)“…Intracerebral hemorrhage (ICH) is a complex and heterogeneous disease, and there is no effective treatment. Spontaneous ICH represents the final manifestation…”
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E2M – Embodied Emotion in Motion: Developing Dancers’ Tools to Explore Sensorimotor Patterns for Emotion and Peak Performance
Published in Avant (Toruń) (01-01-2022)“…This article discusses the results of a practice-as-research intensive project carried out in August 2019, which in turn applies the doctoral research of…”
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Cleavage of Carbon Dioxide C=O Bond Promoted by Nickel‐Boron Cooperativity in a PBP‐Ni Complex
Published in Angewandte Chemie International Edition (21-08-2023)“…The synthesis and characterization of (tBuPBP)Ni(OAc) (5) by insertion of carbon dioxide into the Ni−C bond of (tBuPBP)NiMe (1) is presented. An unexpected CO2…”
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3D chromatin remodelling in the germ line modulates genome evolutionary plasticity
Published in Nature communications (11-05-2022)“…Chromosome folding has profound impacts on gene regulation, whose evolutionary consequences are far from being understood. Here we explore the relationship…”
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Ruthenium Carbene Complexes Analogous to Grubbs‑I Catalysts Featuring Germylenes as Ancillary Ligands
Published in Organometallics (22-10-2018)“…Reactions of the first-generation Grubbs’ catalyst trans-[RuCl2(CHPh)(PCy3)2] (1) with the amidinatogermylenes Ge( t Bu2bzam)R (R = t Bu (L 1 ), CH2SiMe3 (L…”
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Binary and Halide-free Catalyst Systems Based on Al/Ga/In Aminopyridylbisphenolate Complexes for the Cycloaddition of Epoxides and CO2
Published in Inorganic chemistry (19-08-2024)“…Group 13 complexes bearing an aminopyridylbisphenol ligand have been prepared [ML-X; L = ligand, M = Al (X = Cl and Br), Ga (X = Cl, Br, and I), or In (X =…”
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The impact of genetic variations in the serotonergic system on symptom severity and clinical outcome in functional neurological disorders
Published in Journal of psychosomatic research (01-11-2024)“…We studied gene-environment, as well as gene-gene interaction to elucidate their effects on symptom severity and predict clinical outcomes in functional…”
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Redox Potential Determines the Reaction Mechanism of HNO Donors with Mn and Fe Porphyrins: Defining the Better Traps
Published in Inorganic chemistry (21-07-2014)“…Azanone (1HNO, nitroxyl) is a highly reactive molecule with interesting chemical and biological properties. Like nitric oxide (NO), its main biologically…”
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Structural Study of a Flexible Active Site Loop in Human Indoleamine 2,3-Dioxygenase and Its Functional Implications
Published in Biochemistry (Easton) (17-05-2016)“…Human indoleamine 2,3-dioxygenase catalyzes the oxidative cleavage of tryptophan to N-formyl kynurenine, the initial and rate-limiting step in the kynurenine…”
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Amidinatogermylene Metal Complexes as Homogeneous Catalysts in Alcoholic Media
Published in Organometallics (08-08-2016)“…A series of transition-metal complexes containing the bulky amidinatogermylene Ge( t Bu2bzam) t Bu (1; t Bu2bzam = N,N′-bis(tert-butyl)benzamidinate) as a…”
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