以MgCl_2为主的混合盐对2024铝合金大气腐蚀的影响(英文)

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Bibliographic Details
Published in:中国有色金属学报:英文版 no. 4; pp. 1199 - 1208
Main Author: 王彬彬 王振尧 韩薇 汪川 柯伟
Format: Journal Article
Language:English
Published: 2013
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Bibliography:43-1239/TG
Bin-bin WANG, Zhen-yao WANG, Wei HAN, Chuan WANG, Wei KE (State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China)
Atmospheric corrosion of aluminum alloy 2024 (AA2024) with salt lake water was simulated through a laboratory- accelerated test of cyclic wet-dry and electrochemical techniques. Effects of the soluble magnesium salt contained in the salt water were investigated by scanning electron microscope (SEM), transmission electron microscope (TEM), energy dispersive spectrometer (EDS), electron probe micro analyzer (EPMA), X-ray diffraction (XRD), infrared transmission spectroscope (IR), and atmospheric corrosion monitor (ACM). The results showed that, with the deposition, atmospheric corrosion of AA2024 could occur when the relative humidity (RH) was lower than 30%. A main crystalline component of corrosion products, layered double hydroxides (LDH), [Mg1-xAlx(OH)2]^x+ Clx-·mH2O (LDH-C1), was determined, which meant that magnesium ion played an important role in the corrosion process. It not only facilitated the corrosion as a result of deliquescence, but also was involved in the corrosion process as a reactant.
aluminum alloy 2024; atmospheric corrosion; magnesium chloride; relative humidity; corrosion products
ISSN:1003-6326